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The additive guide.

A practical reference for paint and ink technologists: what each family does, how to select and add it, and the terms you’ll meet on a data sheet.

Mechanisms

Three effects behind most coating defects.

Defoaming

Foam is stabilised by surfactants in the bubble wall. A defoamer droplet enters the wall, spreads, thins it and breaks the bubble, releasing the air before the film dries.

Wetting and dispersing

Wetting displaces air from the pigment surface. Dispersing groups then anchor to the particle and keep it apart from its neighbours, electrostatically in water and sterically in solvent.

Surface control

Uneven surface tension pulls a wet film into craters and orange peel. Surface additives concentrate at the film surface and level it out, improving wetting, flow and slip.

Eight families

What each family does.

The same families appear in water-borne and solvent-borne systems, with chemistries tuned to each.

Selection

Choosing the right grade.

Which defoamer?

Mineral-oil types suit flat to mid-sheen, high-PVC emulsion paints. Silicone types suit gloss, low-PVC, clear and industrial systems. Silicone-free polymeric grades suit solvent-free epoxy and PU.

Order of addition

Add wetting and dispersing agents to the grind before the pigment. Add defoamers and surface additives in the let-down.

Confirm the dose

Start within the recommended range and confirm the final level with a ladder study in your own formulation.

In the lab

How to run a ladder study.

  1. Fix the control

    Make one batch without the additive under test.

  2. Build the ladder

    Add the grade at three or four levels across the recommended range.

  3. Test like the real process

    High-speed stirring for foam, roller or spray for micro-foam, drawdowns for levelling.

  4. Measure

    Density loss, grind, colour strength, gloss, craters, viscosity and settling.

  5. Check side effects

    Craters, haze, recoatability and water sensitivity, then re-test after heat-ageing.

  6. Choose the lowest level that works

    Overdosing costs money and can create new defects.

Glossary

Terms on a data sheet.

PVC
Pigment volume concentration: the volume share of pigment and extender in the dry film. High-PVC paints foam and settle differently from glossy low-PVC paints.
APEO-free
Contains no alkylphenol ethoxylates, surfactants restricted in many markets.
VOC-free
Contributes no volatile organic compounds to the formulation.
Amine-neutral
Suitable for systems neutralised with amines without side reactions or odour issues.
Micro-foam
Fine entrapped air that becomes pinholes and haze in the dry film.
Flocculation
Dispersed pigment re-clumping, causing weak colour, floating and low gloss.
Mill-base
The concentrated pigment, dispersant and binder grind before let-down.
Polarity (solvent-borne)
Non-polar, medium-polar and polar systems need different additive chemistries; our tags show where each grade fits.
Thixotropy
Viscosity that drops under shear and recovers at rest, so paint brushes easily yet resists sag.
Solids
The non-volatile share of an additive as supplied, important for dose calculation.

Technical support

Tell us what the formulation is doing. We’ll recommend the grade.

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