Defoaming
Foam is stabilised by surfactants in the bubble wall. A defoamer droplet enters the wall, spreads, thins it and breaks the bubble, releasing the air before the film dries.
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A practical reference for paint and ink technologists: what each family does, how to select and add it, and the terms you’ll meet on a data sheet.
Mechanisms
Foam is stabilised by surfactants in the bubble wall. A defoamer droplet enters the wall, spreads, thins it and breaks the bubble, releasing the air before the film dries.
Wetting displaces air from the pigment surface. Dispersing groups then anchor to the particle and keep it apart from its neighbours, electrostatically in water and sterically in solvent.
Uneven surface tension pulls a wet film into craters and orange peel. Surface additives concentrate at the film surface and level it out, improving wetting, flow and slip.
Eight families
The same families appear in water-borne and solvent-borne systems, with chemistries tuned to each.
Selection
In the lab
Make one batch without the additive under test.
Add the grade at three or four levels across the recommended range.
High-speed stirring for foam, roller or spray for micro-foam, drawdowns for levelling.
Density loss, grind, colour strength, gloss, craters, viscosity and settling.
Craters, haze, recoatability and water sensitivity, then re-test after heat-ageing.
Overdosing costs money and can create new defects.
Glossary
Technical support